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dc.contributor.authorHornink, Milene M.en_US
dc.contributor.authorToledo, Monica F. Z. J.en_US
dc.contributor.authorPimenta, Daniel C.en_US
dc.contributor.authorPaschoalin, Caioen_US
dc.contributor.authorSilva, Pamela M.en_US
dc.contributor.authorFiglino, Giuseppe E.en_US
dc.contributor.authorAguiar, Eurípedesen_US
dc.contributor.authorCervi, Gustavoen_US
dc.contributor.authorRibeiro, Francisco W. M.en_US
dc.contributor.authorCorrera, Thiago Caritaen_US
dc.contributor.authorFerry, Angéliqueen_US
dc.contributor.authorStefani, Hélio A.en_US
dc.date.accessioned2024-09-30T15:16:06Z-
dc.date.available2024-09-30T15:16:06Z-
dc.date.issued2024-
dc.identifier.citationHORNINK, Milene M. , et al. 1-Iodoglycal: a versatile intermediate for the Synthesis of d -Glyco Amides and Esters employing carbonylative cross-coupling reaction. ACS Omega, v. 9, n. 29, p. 31732–31744, 23 jul. 2024.en_US
dc.identifier.issn2470-1343-
dc.identifier.urihttp://repo.saocamilo-sp.br:8080/jspui/handle/123456789/2159-
dc.description.abstractthis study, we present the development of two catalytic processes: a Pd-PEPPSI-catalyzed aminocarbonylation and a Pd(OAc)2-Xantphos-catalyzed alkoxycarbonylation of D-glycals, utilizing carbonylative cross-coupling reactions. We explored successfully various types of aromatic amines, as well as alkyl amines and amino acids, to synthesize new D-glycal amides. However, we observed limitations in the reactivity of alkyl and heteroaromatic amines. The processes enabled the synthesis of 20 novel C1-branched glycoamides and 7 new D-gluco esters.-
dc.publisherACS Publicationsen_US
dc.relation.ispartofACS Omega, v. 9, n. 29, 2024en_US
dc.subjectAmidasen_US
dc.subjectAminasen_US
dc.subjectReações químicasen_US
dc.subjectLipídeosen_US
dc.title1‑Iodoglycal: a versatile intermediate for the Synthesis of D‑Glyco Amides and Esters employing carbonylative cross-coupling Reactionen_US
dc.typeArtigo de Periódicoen_US
dc.identifier.doi10.1021/acsomega.4c02645-
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